Heterogeneous fullerene-supported osmium tetroxide catalyst for the cis-dihydroxylation of olefins.
نویسندگان
چکیده
We report on the activity of fullerene-supported OsO(4) catalysts in the achiral dihydroxylation of olefins using N-methylmorpholine N-oxide as co-oxidant. The fullerene-supported OsO(4) catalysts can selectively dihydroxylate olefins with conversions up to 95% after 48 h without leaching, and the catalysts can be recovered and recycled several times.
منابع مشابه
A Heterogeneous cis-Dihydroxylation Catalyst with Stable, Site-Isolated Osmium ± Diolate Reaction Centers**
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ورودعنوان ژورنال:
- Dalton transactions
دوره 39 34 شماره
صفحات -
تاریخ انتشار 2010